SEPARATION OF ENANTIOMERS OF CHIRAL SULFOXIDES WITH CHLORO-SUBSTITUTED TRIS-PHENYLCARBAMATES OF CELLULOSE AS CHIRAL SELECTORS IN HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

Author: Mari-luiza Konjaria
Co-authors: Natia Shashviashvili
Keywords: Sulfoxide, Stationary phase, high enantioselectivity
Annotation:

The goal of the present project was to screen newly synthesized chiral sulfoxides on their chiral recognition ability with 10 different cellulose phenylcarbamate-based chiral selectors with chloro-substituted in high-performance liquid chromatography. These chiral selectors were also non-commercial products and synthesized in the frame of the present project. In this experiment we have changed the structures of chiral selectors and selectands and got interesting results